Green screens are a pain in the butt.  The problem is lighting.  Everything has to be so flat (no shadows) to come out right.  Then, when placing the subject on a new background, the new background and subject need to have the same lighting, or it's obvious that it's a green screen capture.
You are on the right path.  I started out the same way.  This was my homemade background and "test" shot: 
This is my first purchased backdrop:

This is the backdrop that I use more than any other one:

I would suggest concentrating on photography skills before photoshop.  The "tricks" should come after you have a firm grasp on how to take a perfect picture without needing post editing in photoshop.